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期刊论文 11

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2023 3

2021 2

2014 3

2012 1

2009 1

2008 1

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HSLC钢 1

TRIP钢 1

δ铁素体 1

冷轧基板 1

强化 1

性能 1

组织演化 1

贝氏体相变 1

超级钢 1

软化 1

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A mini-review of ferrites-based photocatalyst on application of hydrogen production

《能源前沿(英文)》 2021年 第15卷 第3期   页码 621-630 doi: 10.1007/s11708-021-0761-0

摘要: Photocatalytic water splitting for hydrogen production is a promising strategy to produce renewable energy and decrease production cost. Spinel-ferrites are potential photocatalysts in photocatalytic reaction system due to their room temperature magnetization, the high thermal and chemical stability, narrow bandgap with broader visible light absorption, and proper conduction band energy level with strong oxidation activity for water or organic compounds. However, the fast recombination of the photoexcited electrons and holes is a critical drawback of ferrites. Therefore, the features of crystallinity, particle size, specific surface area, morphology, and band energy structure have been summarized and investigated to solve this issue. Moreover, composites construction with ferrites and the popular support of TiO2 or g-C3N4 are also summarized to illustrate the advanced improvement in photocatalytic hydrogen production. It has been shown that ferrites could induce the formation of metal ions impurity energy levels in TiO2, and the strong oxidation activity of ferrites could accelerate the oxidation reaction kinetics in both TiO2/ferrites and g-C3N4/ferrites systems. Furthermore, two representative reports of CaFe2O4/MgFe2O4 composite and ZnFe2O4/CdS composite are used to show the efficient heterojunction in a ferrite/ferrite composite and the ability of resistance to photo-corrosion, respectively.

关键词: photocatalyst     spinel-ferrite     composite     photocatalytic hydrogen production    

Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

《化学科学与工程前沿(英文)》 2014年 第8卷 第3期   页码 378-385 doi: 10.1007/s11705-014-1441-y

摘要: Two types of polymeric surfactants, PEG and PVP , were used for the preparation of magnetic ferrite MFe O (M= Mn, Fe) colloidal nanocrystals using a solvothermal reaction method. The effect of spinel type effect on the size evolution of various nanoparticles was investigated. It was found that Fe O nanoparticles exhibited higher crystalinity and size evolution than MnFe O nanoparticles with use of the two surfactants. It is proposed that this observation is due to fewer tendencies of surfactants on the surface of Fe O building blocks nanoparticles than MnFe O . Less amounts of surfactant or capping agent on the surface of nanoparticles lead to the higher crystalibity and larger size. It is also suggested that the type of spinel (normal or inverted spinel) plays a key role on the affinity of the polymeric surfactant on the surface of building blocks.

关键词: spinel type     polymeric surfactant     size evolution     mangnetic ferrite nanoparticle    

Efficient conversion of lignin to alkylphenols over highly stable inverse spinel MnFeO catalysts

《化学科学与工程前沿(英文)》 2023年 第17卷 第8期   页码 1085-1095 doi: 10.1007/s11705-022-2236-1

摘要: The aromatic properties of lignin make it a promising source of valuable chemicals and fuels. Developing efficient and stable catalysts to effectively convert lignin into high-value chemicals is challenging. In this work, MnFe2O4 spinel catalysts with oxygen-rich vacancies and porous distribution were synthesized by a simple solvothermal process and used to catalyze the depolymerization of lignin in an isopropanol solvent system. The specific surface area was 110.5 m2∙g–1, which substantially increased the active sites for lignin depolymerization compared to Fe3O4. The conversion of lignin reached 94%, and the selectivity of alkylphenols exceeded 90% after 5 h at 250 °C. Underpinned by characterizations, products, and density functional theory analysis, the results showed that the catalytic performance of MnFe2O4 was attributed to the composition of Mn and Fe with strong Mn–O–Fe synergy. In addition, the cycling experiments and characterization showed that the depolymerized lignin on MnFe2O4 has excellent cycling stability. Thus, our work provides valuable insights into the mechanism of lignin catalytic depolymerization and paves the way for the industrial-scale application of this process.

关键词: lignin depolymerization     spinel     catalysts     hydrogenation    

Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

《化学科学与工程前沿(英文)》 2023年 第17卷 第12期   页码 2088-2100 doi: 10.1007/s11705-023-2352-6

摘要: Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor application

关键词: nickel ferrite conductivity     carbon oxygen vacancies    

A novel algorithm for frequency dependent modeling of ferrite ring and its optimum design to study VFTO

Mehrdad MAJIDI, Hamid JAVADI, Moein MANBACHI

《能源前沿(英文)》 2014年 第8卷 第1期   页码 90-100 doi: 10.1007/s11708-013-0286-2

摘要: One of the fundamental issues in gas insulated substations (GIS) which has destructive effects on GIS equipment is the very fast transient over-voltages (VFTOs). This paper models a 400/230 kV substation in order to study the effects of VFTO extensively implemented on EMTP-RV. In addition, the application of ferrite rings for suppressing VFTOs is assessed thoroughly. The main advantage of this paper is its new proposed algorithm according to the ferrite ring frequency dependent modeling that is validated with experimental results. This paper examines the effects of three compositions of the ferrite ring on VFTO suppression. Moreover, it estimates the dimension of the ferrite ring based on the SF6 gas insulation withstand and the maximum effect of ferrite rings on VFTO suppression constraint with the COMSOL multiphysics software. Furthermore, it gains VFTO attenuated percentages due to the installation of the ferrite ring in different GIS nodes. Finally, it analyzes the offered VFTO amendment technique in various GIS switching scenarios.

关键词: comsol multiphysics     EMTP-RV     ferrite ring     gas insulated substations (GIS)     transient over-voltage     insulation coordination    

Cu/Cr co-stabilization mechanisms in a simulated AlO-FeO-CrO-CuO waste system

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1408-4

摘要:

• Cu and Cr can be mostly incorporated into CuFexAlyCr2xyO4 with a spinel structure.

关键词: Spinel structure     Copper     Chromium     Co-stabilization     Thermal treatment    

Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

《化学科学与工程前沿(英文)》 2009年 第3卷 第1期   页码 65-67 doi: 10.1007/s11705-009-0105-9

摘要: Lithium is one of the most important light metals, which is widely used as raw materials for large-capacity rechargeable batteries, light aircraft alloys and nuclear fusion fuel. Seawater, which contains 250 billion tons of lithium in total, has thus recently been noticed as a possible resource of lithium. While, since the average concentration of lithium in seawater is quite low (0.17 mg·L ), enriching it to an adequate high density becomes the primary step for industrial applications. The adsorption method is the most prospective technology for increasing the concentration of lithium in liquid. Among the adsorbents for lithium, the ion-sieve is a kind of special absorbent which has high selectivity for Li , especially the spinel manganese oxides (SMO), which among the series of ion-sieves, has become the most promising adsorption material for lithium. In this study, the SMO ion-sieve was prepared by a coprecipitation method. The preparation conditions were discussed and the sample characters were analyzed. Recovery of Li from seawater were studied in batch experiments using prepared ion-sieve, and the effect of solution pH and the uptake rates were also investigated in different Li solutions.

关键词: lithium     ion-sieve     seawater     spinel manganese oxide    

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

《环境科学与工程前沿(英文)》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1696-y

摘要:

● Microwave-assisted catalytic NH3-SCR reaction over spinel oxides is carried out.

关键词: Microwave field     Spinel oxides     NOx     Selective catalytic reduction    

δ-TRIP 钢的物理与力学冶金

易红亮,陈蓬,王国栋,马鸣图

《中国工程科学》 2014年 第16卷 第2期   页码 18-30

摘要:

δ-相变诱发塑性(TRIP)钢具有高的强韧性,可达到第三代汽车钢性能要求,且可电阻点焊,是一种新型的具有较高产业化前景的先进汽车钢。主要阐述了δ-TRIP钢的发展、组织与性能、相变与组织演化机理、强韧性机理、电阻点焊工艺与物理冶金机理。

关键词: TRIP钢     δ铁素体     贝氏体相变     组织演化     性能    

薄板坯连铸连轧铁素体+珠光体类型钢的强化与软化

傅杰,吴华杰,刘阳春

《中国工程科学》 2008年 第10卷 第4期   页码 65-72

摘要:

根据钢的综合强化理论,控制A1附近温度下钢中碳的析出,研究了HSLC钢的强化与软化问题。结果表明:薄板坯连铸连轧HSLC钢,强度还可进一步提高;通过回火缓冷,薄板坯连铸连轧HSLC钢ZJ330的σs从344 MPa降至225 MPa,能满足冷轧基板要求。讨论了有关铁素体轧制、超细晶粒钢以及一种可能的新型建筑材料等问题。

关键词: HSLC钢     强化     软化     冷轧基板     超级钢    

Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis

Yadong GE, Yuanyuan DONG, Shengping WANG, Yujun ZHAO, Jing LV, Xinbin MA

《化学科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 415-422 doi: 10.1007/s11705-012-1214-4

摘要: The catalysts supported on LiAl O (spinel) for vapor phase synthesis of dimethyl carbonate (DMC) from methyl nitrite (MN) have been studied. Their catalytic activities on supports prepared by different methods were evaluated in a continuous reactor. The samples were characterized by powder X-ray diffraction, N adsorption-desorption isotherms, fourier transform infrared spectroscopy and temperature-programmed reduction of H . Li/Al molar ratio and calcination temperature greatly influence the structure of crystalline phase of Li-Al-O oxides. Desirable LiAl O (spinel) was formed at 800°C, while LiAl O (primitive cube) formed at 900°C is undesirable for the reaction. A high Li/Al molar ratio, which was related with LiAlO , also slowed the reaction rate. The electron transfer ability and the interaction with active component are the important properties of the spinel-based supports. The CuCl -PdCl /LiAl O (spinel) with better electron transfer ability and low Pd reduction temperature exhibited a better catalytic ability.

关键词: Wacker-type catalyst     dimethyl carbonate     methyl nitrite     spinel    

标题 作者 时间 类型 操作

A mini-review of ferrites-based photocatalyst on application of hydrogen production

期刊论文

Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

期刊论文

Efficient conversion of lignin to alkylphenols over highly stable inverse spinel MnFeO catalysts

期刊论文

Activated carbon induced oxygen vacancies-engineered nickel ferrite with enhanced conductivity for supercapacitor

期刊论文

A novel algorithm for frequency dependent modeling of ferrite ring and its optimum design to study VFTO

Mehrdad MAJIDI, Hamid JAVADI, Moein MANBACHI

期刊论文

Cu/Cr co-stabilization mechanisms in a simulated AlO-FeO-CrO-CuO waste system

期刊论文

Preparation of lithium ion-sieve and utilizing in recovery of lithium from seawater

Lu WANG, Changgong MENG, Wei MA

期刊论文

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

期刊论文

δ-TRIP 钢的物理与力学冶金

易红亮,陈蓬,王国栋,马鸣图

期刊论文

薄板坯连铸连轧铁素体+珠光体类型钢的强化与软化

傅杰,吴华杰,刘阳春

期刊论文

Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis

Yadong GE, Yuanyuan DONG, Shengping WANG, Yujun ZHAO, Jing LV, Xinbin MA

期刊论文